It has excellent adhesion, as long as the PVC is clean and roughed up.
I completely agree with the above.
One thing I will say: when it starts to part from the epoxy, it is super easy to peel it apart, even if the above is adhered (yuk, yuk, yuk) to.
I have used it as a form to make fiberglass tubes though. I usually coat it with olive oil (common and non-toxic) and then wipe it with a rag before rolling on the FG. It slides out with some effort (but it isn't really resistant to parting).